By Bernard S. Covino Jr.
ASM instruction manual, Vol. 13A: Corrosion: basics, security and Prevention
The goal of ASM instruction manual, quantity 13A: Corrosion: basics, trying out, and safety is to assist engineers and architects comprehend corrosion so we can remedy current corrosion difficulties and forestall destiny ones. it's going to be the 1st booklet you choose whilst gaining knowledge of a corrosion challenge. The insurance of the quantity has been thoroughly revised to make sure that it's the so much accomplished, functional, and up to date source on hand. each one article is listed to different acceptable sections of the instruction manual, and every presents a street map to the hundreds of thousands of person bibliographical references that have been used to assemble the data.
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Additional resources for ASM Handbook: Corrosion : Fundamentals, Testing, and Protection
The potential of any electrode is expressed with respect to the SHE by building (really or virtually) a cell in which the other electrode is a SHE. Consider a typical half-cell reaction with an oxidationreduction (O/R) couple, where O represents the oxidized species and R the reduced species. The cell is represented as: Pt, H2(g)(f = 1 bar)|H+(aq)(a = 1) || O/R (Eq 18) Depending on the position of the O/R electrode on the hydrogen scale, the spontaneous single electrode or halfcell reaction will proceed in one direction or the other: R oxidation: cR → bO + ne- combined with proton reduction: H+(aq) + e- → H2(g); or, O reduction: bO + ne- → cR combined with hydrogen oxidation: H2(g) → H+(aq) + e-.
Freeman, 1964, p 338–360 E. Protopopoff and P. Marcus, Electrode Potentials, Corrosion: Fundamentals, Testing, and Protection, Vol 13A, ASM Handbook, ASM International, 2003, p 8–12 Electrode Potentials E. Protopopoff and P. Marcus, Ecole Nationale Supérieure de Chimie de Paris, Université Pierre et Marie Curie Cell Potentials and the Electromotive Force Series The standard equilibrium potentials measured at 25 °C (77 °F) relative to the SHE for various metal-ion electrodes can be tabulated in a series, called the emf series, shown in Table 1.
Reference electrodes are usually made of a metal immersed in a well-defined electrolyte. In the case of the CuSO4/Cu electrode, the electrolyte is a saturated CuSO 4 aqueous solution; for the SCE, it is a saturated KCl solution. This electrolyte that characterizes the reference electrode must come into contact with the liquid environment of the test electrode to complete the measuring circuit (Fig. 4). There is direct contact between different aqueous media. The difference in chemical composition of the two solutions produces a phenomenon of interdiffusion.